Propyl 2-(3-benzoylthioureido)acetate
نویسندگان
چکیده
The title compound, C(13)H(16)N(2)O(3)S, is a thio-urea derivative with benzoyl and propoxycarbonyl-methyl groups attached to the two terminal N atoms. These groups adopt trans and cis configurations, respectively, with respect to the S atom across the thio-urea C-N bonds. The compound crystallizes in the P2(1)/c space group with Z = 8, resulting in two unique molecules in the asymmetric unit linked by C-H⋯S and C-H⋯O hydrogen bonds, forming a one-dimensional zigzag chain along the c axis.
منابع مشابه
Methyl 3-(3-benzoylthioureido)propanoate
In the title compound, C(12)H(14)N(2)O(3)S, the propyl acetate group and the benzoyl group adopt a cis-trans conformation, respectively, with respect to the thiono S atom across the C-N bonds. The phenyl ring is twisted relative to the the thio-urea mean plane, forming a dihedral angle of 24.16 (9)°. An intra-molecular N-H⋯O hydrogen bond occurs. The crystal packing is stabilized by inter-molec...
متن کاملMethyl 2-(3-benzoylthioureido)acetate
In the title compound, C(11)H(12)N(2)O(3)S, the methyl acetate and benzoyl groups adopt a cis-trans configuration with respect to the thiono S atom across the C-N bonds. An intra-molecular N-H⋯O hydrogen bond is observed. In the crystal packing, mol-ecules are linked by inter-molecular N-H⋯S and C-H⋯O hydrogen bonds to form a two-dimensional network lying parallel to (101).
متن کاملButyl 2-(3-benzoylthioureido)acetate
In the title compound, C(14)H(18)N(2)O(3)S, the butyl acetate fragment and the benzoyl group adopt a cis-trans configuration, respectively, with respect to the thiono S atom across the C-N bonds. In the crystal packing, the mol-ecules are linked by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds to form a one-dimensional chain along the c axis. The terminal butyl C atom is disordered with occupa...
متن کاملOlfactory performance of rats after selective deafferentation of the olfactory bulb by 3-methyl indole.
Rats trained to detect propyl acetate and valeric acid and to discriminate between propyl acetate and amyl acetate and between valeric acid and butyric acid were injected with a low dose of 3-methyl indole, a treatment that produces well-defined and selective deafferentation of the olfactory bulbs. Treatment completely deafferented most but not all bulbar loci for aliphatic acids and at least d...
متن کاملEthyl 2-(3-benzoylthioureido)acetate
The title compound, C(12)H(14)N(2)O(3)S, adopts a cis-trans geometry of the thio-urea group and is stabilized by intra-molecular hydrogen bonds between the carbonyl O atoms and the H atom of the thio-amide group and by a C-H⋯S interaction. Mol-ecules are linked by two inter-molecular hydrogen bonds (C-H⋯O and N-H⋯O), forming a one-dimensional chain parallel to the c axis.
متن کامل